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dc.rights.licenseAl consultar y hacer uso de este recurso, está aceptando las condiciones de uso establecidas por los autores.es_CO
dc.contributor.advisorTéllez Acosta, Gabriel
dc.contributor.advisorHolm, Christian
dc.contributor.advisorLeidy, Chad
dc.contributor.advisorTrizac, Emmanuel
dc.contributor.authorMallarino Robayo, Juan Pablo 
dc.date.accessioned2018-09-27T16:38:55Z
dc.date.available2018-09-27T16:38:55Z
dc.date.issued2013
dc.identifier.urihttp://hdl.handle.net/1992/7808
dc.description.abstract"The present thesis is the recompilation of several projects developed during the last three years in rod-like polyelectrolytes in the special no-salt case in the cell model. Our work presents contributions to the strong association regime in two and three dimensions as well as a measure of the condensation phenomenon at all levels. The models were contrasted against numerical results from Monte Carlo simulations. We obtained that Manning condensation in three dimensions is overestimated above the ideal value (1-1Ç) as a result of small box sizes and large couplings. For couplings beneath a threshold ([I] < 90), the condensation is that predicted by Manning. In two dimensions, the thermodynamic limit recovers the results for mean field. Conversely, with a finite number of counter-ions, the system undergoes a series of transitions corresponding to the binding of each individual charge; consequently, the strong coupling regime comes with full condensation. In both two and three dimensions the onset for condensation reads in terms of the Manning parameter as Ç = 1."es_CO
dc.formatapplication/pdfes_CO
dc.format.extent252 hojases_CO
dc.language.isospaes_CO
dc.publisherUniandeses_CO
dc.sourceinstname:Universidad de los Andeses_CO
dc.sourcereponame:Repositorio Institucional Sénecaes_CO
dc.titleCondensation in rod-like polyelectrolytes - the no-salt solution casees_CO
dc.typedoctoralThesises_CO
dc.publisher.programDoctorado en Ciencias - Físicaes_CO
dc.rights.accessRightsopenAccess
dc.subject.keywordCondensación - Investigacioneses_CO
dc.subject.keywordPolielectrolitos - Investigacioneses_CO
dc.publisher.facultyFacultad de Cienciases_CO
dc.publisher.departmentDepartamento de Físicaes_CO
dc.type.versionpublishedVersion
dc.description.degreenameDoctor en Ciencias - Físicaes_CO
dc.description.degreelevelDoctoradoes_CO


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